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Paper Roses

(7,473 posts)
Thu Jun 12, 2014, 08:12 AM Jun 2014

I need stain removal help--big time!

Idiot that I am, I managed to get silver nitrate in my Formica counter top.
A distraction caused me to drop the item I was testing. As a consequence, the silver nitrate got on the counter top. The Formica is beige and now has several purple stains and it looks terrible. I have a slurry of baking soda/water on it now but I am afraid this will not do the job.
I know better, been using this material for years. I always have newspaper layers under my work but you know how it goes, the one time I didn't......

The solution was from a silver testing kit. Good use instructions but no advice on the data sheets about how to remove a messy stain.

Of course, this happened a week after having a realtor here to discuss the sale of my house. Now I have a eyesore.

Any help would be appreciated. I have Googled but have not been able to find a good answer.

4 replies = new reply since forum marked as read
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I need stain removal help--big time! (Original Post) Paper Roses Jun 2014 OP
Straight Clorox might bleach the stain out Warpy Jun 2014 #1
^^^ this ^^^^^ NMDemDist2 Jun 2014 #2
A reference here: politicat Jun 2014 #3
Thank you! What great information. Paper Roses Jun 2014 #4

Warpy

(111,224 posts)
1. Straight Clorox might bleach the stain out
Thu Jun 12, 2014, 09:08 AM
Jun 2014

but it will also bleach the countertop. Baking soda will do squat. Ditto vinegar, peroxide, and ammonia. There are resurfacing kits for formica (basically paint) if you want to go that route.

Get an estimate on replacing the countertop with something more trendy. It usually doesn't cost an arm and a leg and could help the house sell.

NMDemDist2

(49,313 posts)
2. ^^^ this ^^^^^
Fri Jun 13, 2014, 07:19 PM
Jun 2014

when i sold my house i was amazed how cheap a new laminate top was. couldn't believe i lived with pink countertops for all those years....

politicat

(9,808 posts)
3. A reference here:
Fri Jun 13, 2014, 11:46 PM
Jun 2014
http://www.bostick-sullivan.com/articles/silvernitrate.html

Stains can be removed from some materials with a permanganate and bisulfite treatment. It will vary in effectiveness depending on the material, of course. Wash the material in potassium permanganate, of 1 teaspoon to a pint of water. The material will turn dark red brown. This can be a little unsettling. Using 1 teaspoon of sodium bisulfite to a pint of water, rinse the material in this and the red color will immediately and completely disappear. There may be a slight release of sulfur dioxide gas, which is pungent, so this should be done in a ventilated area. I probably could have removed the stain in our sink had I know about this treatment.


Potassium permanganate can be purchased at DIY/home improvement stores in the water softener section (it's used for cleaning them). Check with your preferred first. Sodium bisulfite can be bought at home brew shops -- it's used to sanitize brew and wine tanks.

Time is not on your side here, I am sorry to say.

Another suggestion from wet etch glass plate photographers is:
Try a little tincture of iodine on the stain first.
Then use thiosulfate or cyanide fixer on the stain. (Photography shops may still carry, but be warned -- poison.)
The iodine converts the silver to silver iodide making it soluble in your fixing solution. Works on hand stains also.


ETA: found one more reference:
I want to thank you for suggesting Jeweler's Rouge because it led me to experiment by applying regular silver polish (Wright's Silver Cream) to the silver nitrate stains. This worked well, removing 90% or more of the visible stain on first application. The product MSDS lists only two components: microcrystalline silica and sodium carbonate [soda ash!]

There are probably other ways to lift silver nitrate stains from hard surfaces. I didn't think to try a powdered cleanser, such as Bon Ami, before the experiment, so am unable to judge its effectiveness; nor was iron oxide paste (Jeweller's Rouge) tried. The sodium hypochlorite, surfactants and carboxylic acids in the dishwashing liquid, bleach and spray cleaner had no obvious effect, but constituent strength (household concentrations) and duration of contact (< 1 min.) preclude negative inference.

Paper Roses

(7,473 posts)
4. Thank you! What great information.
Sat Jun 14, 2014, 07:01 PM
Jun 2014

Tomorrow I start the real work on the counter. I can't believe I did such a stupid thing. Your research and information is of great help to me. A trip to Home Depot will hopefully get me the materials I need. My other option will be to paint the counter with one of the new Formica paint products.

My funds are limited so I cannot have the counter top replaced. This counter had been in great shape for the 45 years since we bought this old house and put in the kitchen. How ironic that I ruined the top 4 days after the realtor looked at the house to potential sale. Sometimes I wonder if I am losing it. I know better than to allow this to have happened.

I'll keep you posted.

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