NON-TECHNICAL SUMMARY: A high concentration of dairy farms in central Texas has caused degradation of waterways with excess nutrient runoff. Conventional methods of controlling manure pollution are not sufficiently effective. The MixAlco process may be an economically feasible method of treating manure wastes while at the same time producing products of value for fuel and chemical markets. The purpose of this project is to evaluate the MixAlco process for treatment of cattle wastes and to learn more about the microbial ecosystems present in the reactors.
OBJECTIVES: The application seeks to secure funding toward the purchase of a gas chromatograph for researching the conversion of fiber and manure to fuels and chemicals. The GC will be used to analyze for carboxylic acids and gas components emanating from an acidogenic digester. Previous work on the MixAlco process has established GC as the method of choice for analysis of fermentation products: it can analyze products in both the gas and liquid phases and is sufficiently robust to handle raw samples. Primary objectives of the proposed research project are to: 1) Apply the acidogenic digestion to conversion of cattle wastes, monitoring fermentation products with respect to digester operating conditions, and 2) Characterize the microbial populations present in the fermentations. Correlations between the microbial population structures and growth conditions will be determined.
APPROACH: A non-sterile acidogenic fermentation will be applied to cattle manure, with the goal of quantifying the productivity of the acid generation in response to different growth conditions. This digester is at the heart of the MixAlco process, which converts organic wastes to carboxylic acids, ketones and alcohols. To maintain high acid yields in the digester, methane generation must be suppressed. Thus two measurements that are critical to evaluation of the process are the concentrations of organic acids in the liquid phase and methane in the gas phase. The GC applied for in this proposal will be used to do both these measurements. The microbial populations present in the MixAlco digesters will be characterized using the BioLog identification system. To date the populations in the digester have been characterized in only the most general terms, such as the culture's origin (marine or terrestrial) and optimal growing temperature (mesophillic or thermophillic). Two characteristics that are required for effective performance of the fermentation are a high degree of salt tolerance and a low productivity of methane. Thus, improving the fundamental identification of the organisms present may enable further understanding and improvements of the microbial process.
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All the steps in the MixAlco process have been proven at the laboratory scale. A techno-economic model of the process indicates that with the tipping fees available in New York (126 dollars/dry tonne), mixed alcohol fuels may be sold for 0.04 dollars/L (0.16 dollars/gal) with a 60% return on investment (ROI). With the average tipping fee in the United States rates (63 dollars/dry tonne), mixed alcohol fuels may be sold for 0.18 dollars/L (0.69 dollars/gal) with a 15% ROI. In the case of sugarcane bagasse, which may be obtained for about 26 dollars/dry ton, mixed alcohol fuels may be sold for 0.29 dollars/L (1.09 dollars/gal) with a 15% ROI.
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http://www.fuelandfiber.com/Archive/Fuel/Research/Holtzapple/holtzapple.html Biomass technology answers biofuels need, Texas A&M chemical engineer says
2/20/2000
It generally takes 50 years for an energy technology to go from laboratory development to significant economic impact," says Holtzapple. "Some analysts project that global oil production will peak in 2010 or 2020. Many forecasters fear the United States is already behind in developing biofuels."
To help address this problem, the Clinton administration's budget proposal earlier this month includes $2.1 billion to help promote biofuels during the next decade.
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http://aiche.confex.com/aiche/2005/techprogram/P14000.HTMWednesday, 2 November 2005 - 2:10 PM
Application of the Mixalco Process to in-Situ Conversion of Dairy Manure and Chipped Yard Waste for Production of Fuels and Chemicals
Reactor Engineering for Biomass Feedstocks
http://aiche.confex.com/aiche/2005/techprogram/S1421.HTMEnvisioning Borefineries
http://aiche.confex.com/aiche/2005/techprogram/D1027.HTM