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Edited on Fri Apr-09-04 08:40 PM by NNadir
Almost all of it is Plutonium-244 found (on an atomic level) in old Thorium ores in California. The amount of it is so small, that it is literally confined to a few atoms. Plutonium-244 (half-life 80 million years) was probably found in fair quantities on earth for several hundred million years after it's formation, although all of it effectively has now decayed to radioactive Thorium-232. Tiny, although largely undectable, amounts of Plutonium-239 are formed from the neutron fluxes that occur in natural Uranium ores. About 1.8 billion years ago, neutron fluxes in Uranium ores were so high that naturally occurring nuclear reactors, about 15 of them, ran for hundreds of thousands of years in a place called Oklo, Gabon. These undoubtably generated considerable heat, but the decay of Uranium-235 over hundreds of millions of years now makes naturally occuring nuclear reactors impossible.
The internal heat of the earth today derives from five radioactive decay chains. One is that Uranium-238 and all of its daughters (Thorium-234, Protactinium-234, Uranium-234, Thorium-230, Radon-226, Radon-222, Polonium-218, lead-214, Bismuth 214, Polonium-214, Lead-210, Bismuth-210, Polonium-210). The latter decays to stable lead 206. For Thorium-232 the decay chain is similar. The Uranium-235 decay chain is more complex and includes all of the above elements plus tiny fractions of the extremely radioactive elements Actinium and Francium. Two other elements contribute heat, potassium-40, (which is the primary source of natural physiological radioactivity found in all living tissue) and Rubidium-87. The majority of the potassium-40 found on the earth at the time of its formation has now decayed to Argon, where it constitutes a significant portion of the atmosphere. The remaining potassium-40 is still a relatively important source of the internal heat of the earth, though not nearly as important as the Uranium and Thorium decay chains. Rubidium-87 generates an almost insignificant portion of the heat, but it is a fair constituent of the radioactivity of natural tissues. (Rubidium mimics potassium very closely in its chemistry and is present in all living tissue, though it has no known physiological purpose.)
Some radioactive elements are also formed constantly in earth's atmosphere. The most famous is Carbon-14, which is formed in the upper atmosphere as a result of nuclear reactions deriving from interaction with high energy solar particles with Nitrogen. In this reaction, neutrons produced by the sun or by the interaction of cosmic rays and atmospheric atoms ("spallation" reactions) hit Nitrogen-14 causing it to eject a proton (a hydrogen ion). The rate of formation and decay of carbon-14 has long been at equilibrium, it decays as fast as it is formed, and this equilibrium establishes the atomic clock in radiocarbon dating.
Another radioactive element formed in the upper atmosphere in measurable quantities is Krypton-85. Naturally occuring Krypton-84 in the atmosphere is hit by neutrons (from the same source as with carbon-14) and transformed into Krypton-85. The majority of the Krypton-85 found on earth today, however derives from nuclear testing and nuclear power plants. (Krypton-85 is the only normal radioactive release of nuclear power plants.)
About 18 grams of radioactive tritium, a form of hydrogen, is produced each year from interaction of solar neutrons with deuterium that is naturally found in water.
Radioactive phosphorus does not naturally occur on earth. All that is present in the environment is the result of leaks from laboratories (where it is an important tracer in biochemical studies, particularly of DNA).
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