The challenges that fuel cells fail to meet. I wrote it because I posted information on a new type of energy storage that looks like a real step forward, and the people who llike this fuel cell tried to say the battery isn't significant but the Bloom box was. (BTW, I do not advocate investing money in either technology or company as they are both, for different reasons, extremely risky.) This is my response:
The challenges that fuel cells fail to meet.
What is the difference between energy storage and energy generation? If I have a gallon of gasoline I have X amount of energy stored in a container. If I have a charged lithium battery pack I have X amount of energy stored in a container.
If I need to use this energy for something I have to convert it to power. An internal combustion engine converts the solar energy stored chemically in the gasoline to heat and mechanical energy. The heat is largely wasted and losses to heat accounts for 70-88% ff the gasoline's energy.
If I use fuel cell, I have to run the gasoline (or natural gas etc) through a "reformer" and change the nature of the stored energy from one chemistry to a different chemistry. This results in lost energy, but now I can use a fuel cell to process the chemical energy into electricity and heat. Total losses for process in the fuel cells now on the market are around 60-80% of the energy contained in the gasoline. For the Bloom box the loss is stated to be 52%.
Another term to be familiar with is "energy carrier". That describes the portability characteristic that is associated with liquid fuels, but you should remember that liquid fuels are really stored energy. While the portability factor is the one most people focus on for gasoline, it's important to bear the fact that it is stored energy in mind because when we seek an alternative to gasoline, we are dealing with both the storage issue and with the portability issue. I can store a lot of energy cheaply in a pumped hydro system, but I can't carry that around in my car.
So the application is very important when evaluating these technologies. In the case of fuel cells, the efficiency of the fuel cell with a reformer is better than an internal combustion engine, but it still emits a lot of CO2. We can get the portability but we are using stored energy in fossil fuels and that means CO2.
An alternative is to operate a separate process that uses electricity (from fossil, renewables, or nuclear) to produce pure hydrogen. Of course, that incurs an energy loss from whatever energy state we begin with. The H2 then must be made portable. That incurs another loss. When pure H2 is used in a fuel cell, the conversion efficiency is about 50-60%, meaning we lose 40-50% as heat. But when we look at the process of getting the H2 to the fuel cell.
The alternative for automobiles (where portability is important) is the use of lithium batteries. When we track the same route for energy made portable by storage in lithium batteries as we do for fuel cells, this is what we find. Starting with 100kwh of electricity, for the two methods of making H2 portable for the fuel cell we end up with between 19-23kwh pushing the vehicle down the road; starting with the same 100 KWH for batteries we end up with 69kwh pushing the vehicle down the road - it is simply no contest.
From "Why a Hydrogen Economy Doesn't Make Sense" at
http://www.physorg.com/news85074285.htmlThis chart is 4 years old, so there are some improvements on both sides of the chart, but there is nothing that has been developed that alters the basic relationship that strongly favors batteries.
If we look for applications outside the transportation sector, we need to ask how relevant the portability factor is. If we are looking for a system for our home, business or local housing development, what are the characteristics the system must possess to best meet our needs?
I'd argue that the first point is that it should be carbon neutral. If we are not concerned about carbon, the present grid system is pretty darned good at meeting our energy needs for home use. But if we move to carbon free energy what then? The use of nuclear power fits into the present grid system so we can make the transition by building an additional 400-500 nuclear plants in the US and changing nothing else. To use that strategy throughout the world will require about 17,000 nuclear plants.
The vast majority of independent energy policy analysts do not see that as a viable strategy for a number of reasons. There are quite a few plans for making a transition away from fossil fuels and very few from outside of the nuclear industry advocate for expansion of our nuclear fleet. The particulars of that argument are not relevant for this discussion about applications for energy storage and recovery within a distributed grid system, which would be built around renewables. If we go with the nuclear option, the use of fuel cells from any maker have little value.
So (presuming you are interested in a transition to renewables) what about using fuel cells to meet needs at the home, business or local housing development level?
At the home level the chance seems fairly low since the same efficiency issue with input is at play. In our chart above, we find the answer at the level above the end use level for we want to compare the output of the device delivering the electricty, not what the final efficiency through our refrigerator might be, right? The chart gives us an efficiency range of 21-26% for the fuel cell and 77% for the lithium batteries.
If we go to larger scale systems we are looking at the same issue, only the battery is different. For transportation lithium is best because it sores a lot of energy by weight and volume compared to other types of batteries. But for these stationary applications in the microgeneration range, there are other batteries that are very functional.
What about biofuels? They also have to go through a reformer for the fuel cell and when they do, the fuel cell compares poorly to combined cycle gas turbines in the area of efficiency.
The bottom line is that with a fuel cell because you have to go from electricity, to chemical and back to electricity, the system efficiency is too low. If we look at using the fuel cell with hydrocarbons, then it must go through the reformer, and that is even worse than if we manufacture H2.
If we use of manufactured H2 from renewable sources we have essentially no carbon carbon emissions. But there is still the low efficiency rating. We can use the same no carbon renewable sources with batteries of all sorts much more efficiently.
That's why the low cost, scalable rock battery at 72-80% round trip efficiency that can be used anywhere is a breakthough and why a new iteration of an old design of the fuel cell isn't.
http://www.greentechmedia.com/articles/read/breakthrough-in-utility-scale-energy-storage-isentropic